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Cadmium oxide : ウィキペディア英語版
Cadmium oxide

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Cadmium oxide is an inorganic compound with the formula CdO. It is one of the main precursors to other cadmium compounds. It crystallizes in a cubic rocksalt lattice like sodium chloride, with octahedral cation and anion centers.〔Wells, A.F. (1984) Structural Inorganic Chemistry, Oxford: Clarendon Press. ISBN 0-19-855370-6.〕 It occurs naturally as the rare mineral monteponite. Cadmium oxide can be found as a colorless amorphous powder or as brown or red crystals.〔Lewis, Richard J., Sr., Hawley's condensed chemical dictionary, 13th ed., 1997, p. 189〕 Cadmium oxide is an n-type semiconductor with a band gap of 2.18 eV (2.31 eV) at room temperature (0 K).
==Production and structure==
Since cadmium compounds are often found in association with zinc ores, cadmium oxide is a common by-product of zinc refining. It is produced by burning elemental cadmium in air. Pyrolysis of other cadmium compounds, such as the nitrate or the carbonate, also affords this oxide. When pure, it is red but CdO is unusual in being available in many differing colours due to its tendency to form defect structures resulting from anion vacancies.〔Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.〕 Cadmium oxide is prepared commercially by oxidizing cadmium vapor in air.

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